Roger Federer SUI (1) vs. Sam Querrey USA
Albert Montanes ESP vs. Kristof Vliegen BEL
Q-Victor Crivoi ROU vs. Q-David Marrero ESP
Mario Ancic CRO vs. Andreas Seppi ITA (31)
Ivo Karlovic CRO (20) vs. Alejandro Falla COL
Julien Benneteau FRA vs. Vincent Spadea USA
Mischa Zverev GER vs. Q-Paul Capdeville CHI
Robin Soderling SWE vs. Juan Monaco ARG (13)
Stanislas Wawrinka SUI (9) vs. Philipp Kohlschreiber GER
Marin Cilic CRO vs. Robin Haase NED
LL-Pablo Andujar ESP vs. Filippo Volandri ITA
Pablo Cuevas URU vs. Fernando Gonzalez CHI (24)
Igor Andreev RUS (27) vs. Potito Starace ITA
Donald Young USA vs. Robby Ginepri USA
Dudi Sela ISR vs. Victor Hanescu ROU
Florent Serra FRA vs. Richard Gasquet FRA (8)