共有十位女選手參加2014法網單打會外賽，
與男單一樣都是日本選手最多，共有六位。
(1)Irina-Camelia Begu v 江口実沙
(wc)Storm Sanders v Aleksandra Krunic
Florencia Molinero v Ayumi Morita
Eva Birnerova v (20)Grace Min
(3)Timea Babos v Maria Irigoyen
Indy de Vroome v Kateryna Bondarenko
Diana Marcinkevica v Maryna Zanevska
Nastassja Burnett v (21)鄭賽賽
(5)Danka Kovinic v (wc)Stephanie Foretz Gacon
瀬間詠里花 v Ana Konjuh
Anabel Medina Garrigues v (wc)Jade Suvrijn
Tereza Smitkova v (17)Victoria Duval
(6)謝淑薇 v Cagla Buyukakcay
Alberta Brianti v Evgeniya Rodina
Aleksandra Wozniak v Melanie Klaffner
Alexandra Dulgheru v (15)Lara Arruabarrena
(7)Mariana Duque-Marino v Yulia Putintseva
穗積絵莉 v Viktorija Golubic
Melanie Oudin v (wc)Manon Arcangioli
Kiki Bertens v (18)Lucie Hradecka
(8)Magda Linette v Ksenia Pervak
Irena Pavlovic v Marta Sirotkina
Chanel Simmonds v Jarmila Gajdosova
日比万葉 v (14)Vesna Dolonc
(9)Timea Bacsinszky v Richel Hogenkamp
Arantxa Rus v Lyudmyla Kichenok
Sesil Karatantcheva v Stephanie Vogt
Laura Siegemund v (13)Andrea Hlavackova
(12)Kristyna Pliskova v Anastasiya Vasylyeva
Carina Witthoeft v 尾崎里紗
Tamira Paszek v Andreea Mitu
Katerina Siniakova v (22)Tadeja Majeric